KINETICS AND MECHANISM OF CATALYTIC HYDROXYLATION OF PHENOL BY HYDROGEN-PEROXIDE .1. GENERAL RELATIONSHIPS OF PROCESS VARIABLES

Authors
LITVINTSEV IY MITNIK YV MIKHAILYUK AI TIMOFEEV SV SAPUNOV VN
Citation
Iy. Litvintsev et al., KINETICS AND MECHANISM OF CATALYTIC HYDROXYLATION OF PHENOL BY HYDROGEN-PEROXIDE .1. GENERAL RELATIONSHIPS OF PROCESS VARIABLES, Kinetics and catalysis, 34(1), 1993, pp. 71-75
Citations number
13
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
34
Issue
1
Year of publication
1993
Part
1
Pages
71 - 75
Database
ISI
SICI code
0023-1584(1993)34:1<71:KAMOCH>2.0.ZU;2-P
Abstract
Various types of homogeneous catalysts have been investigated to deter mine their influence on the rate and selectivity of hydroxylation of p henol by hydrogen peroxide. General relationships in the course of the process have been established - relationships that are also character istic for a number of monosubstituted derivatives of phenol. The influ ence of initial parameters on the length of the induction period has b een investigated, and a mechanism is proposed for the induction period .