KINETICS AND MECHANISM OF CATALYTIC HYDROXYLATION OF PHENOL BY HYDROGEN-PEROXIDE .2. MODELING OF THE INITIAL-STAGE IN THE PRESENCE OF CATALYTIC-SYSTEM FE2- INFLUENCE OF CONCENTRATIONS OF INITIAL REACTANTS( PYROCATECHOL )

Authors
LITVINTSEV IY MITNIK YV MIKHAILYUK AI TIMOFEEV SV SAPUNOV VN
Citation
Iy. Litvintsev et al., KINETICS AND MECHANISM OF CATALYTIC HYDROXYLATION OF PHENOL BY HYDROGEN-PEROXIDE .2. MODELING OF THE INITIAL-STAGE IN THE PRESENCE OF CATALYTIC-SYSTEM FE2- INFLUENCE OF CONCENTRATIONS OF INITIAL REACTANTS( PYROCATECHOL ), Kinetics and catalysis, 34(1), 1993, pp. 76-82
Citations number
4
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
34
Issue
1
Year of publication
1993
Part
1
Pages
76 - 82
Database
ISI
SICI code
0023-1584(1993)34:1<76:KAMOCH>2.0.ZU;2-K
Abstract
A detailed kinetic study has been made of the hydroxylation of phenol by hydrogen peroxide with a previously prepared iron sulfate-pyrocatec hol complex as the catalyst. By means of the initial rate method, a mo del has been obtained, giving an adequate description of all of the ob served relationships within the intervals of variation of initial conc entrations that were investigated. phenol 0.25-3 M, hydrogen peroxide 0.25-3 M.