STRUCTURE, ELECTRONIC-SPECTRUM AND ANGULAR-OVERLAP BONDING PARAMETERSOF L-1-YL)(2-THIENYL)METHANE](NITRATO-O,O')NICKEL(II) NITRATE

Authors
ASTLEY T HITCHMAN MA SKELTON BW WHITE AH
Citation
T. Astley et al., STRUCTURE, ELECTRONIC-SPECTRUM AND ANGULAR-OVERLAP BONDING PARAMETERSOF L-1-YL)(2-THIENYL)METHANE](NITRATO-O,O')NICKEL(II) NITRATE, Australian Journal of Chemistry, 50(2), 1997, pp. 145-148
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Australian Journal of Chemistry → ACNP
ISSN journal
00049425
Volume
50
Issue
2
Year of publication
1997
Pages
145 - 148
Database
ISI
SICI code
0004-9425(1997)50:2<145:SEAABP>2.0.ZU;2-I
Abstract
The crystal structure of the complex [Ni(pz(2)thCH)(2)(O(O')NO '')]NO3 has been determined by X-ray diffraction, where pz and th represent t he pyrazolyl and thienyl groups of a potentially tripodal ligand. The thienyl groups are not bound to the metal, which is coordinated to fou r pyrazolyl groups and a chelating nitrate ion. The electronic 'd-d' t ransition energies are interpreted in terms of angular-overlap bonding parameters which agree well with those reported for other similar com plexes.