ASYMMETRIC EPOXIDATION WITH OPTICALLY-ACTIVE (SALEN)MANGANESE(III) COMPLEXES - FROM WHICH DIRECTION DOES THE OLEFIN APPROACH THE METAL-OXO BOND

Authors
HOSOYA N HATAYAMA A YANAI K FUJII H IRIE R KATSUKI T
Citation
N. Hosoya et al., ASYMMETRIC EPOXIDATION WITH OPTICALLY-ACTIVE (SALEN)MANGANESE(III) COMPLEXES - FROM WHICH DIRECTION DOES THE OLEFIN APPROACH THE METAL-OXO BOND, Synlett, (9), 1993, pp. 641-645
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
9
Year of publication
1993
Pages
641 - 645
Database
ISI
SICI code
0936-5214(1993):9<641:AEWO(C>2.0.ZU;2-O
Abstract
Asymmetric epoxidation of trans-stilbene, cis-beta-methylstyrene, dihy dronaphthalene, and 6-acetamido-2,2-dimethyl-7-nitrochromene was exami ned with various optically active (salen)manganese(III) complexes as c atalysts. From the results, it was strongly suggested that cis-olefin approaches metal-oxo bond along nitrogen-metal bond axis.