REGIOCONTROL AND STEREOCONTROL IN THE REDUCTIVE RING-OPENING OF THE SPIROCYCLIC EPOXIDE DERIVED FROM THE 4-SILOXY-2-CYCLOPENTENONE

Authors
TOMOOKA K ISHIKAWA K ALMASUM M NAKAI T
Citation
K. Tomooka et al., REGIOCONTROL AND STEREOCONTROL IN THE REDUCTIVE RING-OPENING OF THE SPIROCYCLIC EPOXIDE DERIVED FROM THE 4-SILOXY-2-CYCLOPENTENONE, Synlett, (9), 1993, pp. 645-646
Citations number
3
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
9
Year of publication
1993
Pages
645 - 646
Database
ISI
SICI code
0936-5214(1993):9<645:RASITR>2.0.ZU;2-#
Abstract
Reductions of the title epoxide with DIBAL, NaBH4, and LiBEt3H are sho wn to afford the cis-3-hydroxymethyl-5-siloxy-1-cyclopentene, 2-hydrox ymethyl-4-siloxy-1-cyclopentene, and the 1-methyl-4-siloxy-2-cyclopent ene-1-ol, respectively, in a high selectivity.