ELABORATION OF 3,4-DIHYDRO-2H-PYRAN VIA ETA-2-(3-OXACYCLOHEXYNE) ZIRCONOCENE

Citation
Mcj. Harris et al., ELABORATION OF 3,4-DIHYDRO-2H-PYRAN VIA ETA-2-(3-OXACYCLOHEXYNE) ZIRCONOCENE, Synlett, (9), 1993, pp. 705-707
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
09365214
Issue
9
Year of publication
1993
Pages
705 - 707
Database
ISI
SICI code
0936-5214(1993):9<705:EO3VEZ>2.0.ZU;2-W
Abstract
Beta-hydrogen activation via loss of methane from 6-(zirconocene(methy l))-3,4-dihydro-2H-pyran affords eta2-(3-oxacyclohexyne)-zirconocene w hich inserts unactivated alkenes and alkynes to afford elaborated dihy dropyrans on aqueous work-up.