IRON-PROMOTED DEAMINATION REACTIONS OF N-SUBSTITUTED 7-AZANORBORNADIENE DERIVATIVES

Authors
CHOW TJ HWANG JJ SUN CH DING MF
Citation
Tj. Chow et al., IRON-PROMOTED DEAMINATION REACTIONS OF N-SUBSTITUTED 7-AZANORBORNADIENE DERIVATIVES, Organometallics, 12(9), 1993, pp. 3762-3765
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
12
Issue
9
Year of publication
1993
Pages
3762 - 3765
Database
ISI
SICI code
0276-7333(1993)12:9<3762:IDRON7>2.0.ZU;2-R
Abstract
Summary: Two types of metallic intermediates were observed in the iron -promoted deamination reactions of N-substituted 7-azanorbornadiene (A NBD) derivatives, i.e., (ANBD)Fe(CO)4 formed first, followed by (ANBD) -Fe(CO)3. The latter can also be prepared alternatively from the forme r by reacting with trimethylamine N-oxide. Their spectroscopic charact eristics as well as their roles in the deamination mechanisms were ana lyzed.