FLOW-VACUUM PYROLYSIS OF POLYCYCLIC COMPOUNDS .5. PYROLYSIS OF 5-(BETA-ACETOXYETHYL)-5H-DIBENZO[A,D]CYCLOHEPTENE AND OF 5-(BETA-HYDROXYETHYL)-5H-DIBENZO[A,D]CYCLOHEPTENE

Authors
BANCIU MD STAN S BANCIU A PETRIDE A FLOREA C
Citation
Md. Banciu et al., FLOW-VACUUM PYROLYSIS OF POLYCYCLIC COMPOUNDS .5. PYROLYSIS OF 5-(BETA-ACETOXYETHYL)-5H-DIBENZO[A,D]CYCLOHEPTENE AND OF 5-(BETA-HYDROXYETHYL)-5H-DIBENZO[A,D]CYCLOHEPTENE, Revue Roumaine de Chimie, 38(4), 1993, pp. 469-473
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Revue Roumaine de Chimie → ACNP
ISSN journal
00353930
Volume
38
Issue
4
Year of publication
1993
Pages
469 - 473
Database
ISI
SICI code
0035-3930(1993)38:4<469:FPOPC.>2.0.ZU;2-K
Abstract
Flow-vacuum pyrolyses of the title compounds 11 and 12 afford product distributions similar to pyrolyses of corresponding isomeric acetates or alcohols with 10,11-dihydro-5,10-ethano-5H-dibenzo[a, d]cyclohepten e skeleton (1, 3) and 9,10-dihydro-9,10-propanoanthracene skeleton (2 and 4). A radical mechanism is suggested for pyrolyses of 11 and 12.