Ja. Kunc, ANALYTICAL DEPENDENCE OF THE VISCOSITY CROSS-SECTIONS AND VISCOSITY COEFFICIENTS ON PARAMETERS OF INTERMOLECULAR POTENTIALS, The Journal of chemical physics, 99(6), 1993, pp. 4705-4717
General analytical expressions for viscosity cross sections and viscos
ity coefficients of gases as functions of the parameters of intermolec
ular potentials are derived from the first principle using the classic
al scattering theory. Two types (one repulsive-attractive and one pure
ly repulsive) of the central-force potentials, suitable to represent m
olecule-molecule, atom-molecule and atom-atom interactions, are consid
ered. The expressions for viscosity show good agreement with results o
f numerical calculations in high-temperature single-component gases (a
bove 2000 K) where viscosity measurements are not available.