OXIDATION OF METHANE, BUTANE AND CARBON-MONOXIDE ON AL-FE OXIDE CATALYSTS

Authors
TASKINA SY KIRICHENKO OA CHERMASHENTSEVA GK
Citation
Sy. Taskina et al., OXIDATION OF METHANE, BUTANE AND CARBON-MONOXIDE ON AL-FE OXIDE CATALYSTS, Reaction kinetics and catalysis letters, 49(2), 1993, pp. 235-240
Citations number
4
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
49
Issue
2
Year of publication
1993
Pages
235 - 240
Database
ISI
SICI code
0133-1736(1993)49:2<235:OOMBAC>2.0.ZU;2-2
Abstract
The activity of the catalysts obtained by supporting Fe3+ oxalate comp lexes on alpha- and gamma-Al2O3 in oxidation of CH4, C4H10 and CO has been studied. The composition of the impregnating solution and the tem perature of catalyst thermal treatment were varied. The most active ca talysts were prepared by impregnation of gamma-Al2O3 with (NH4)3Fe(C2 O4)3! solutions at pH=2.0-3.5. Their activity appeals to be close to t hat of Al-Mg-Cr catalysts in butane oxidation and even exceeds this in CO oxidation.