PREPARATION AND PROPERTIES OF THE DINUCLEAR COPPER(II) COMPLEXES CONTAINING THE DERIVATIVES OF S(2-BENZIMIDAZOLYL)!-2-HYDROXY-1,3-DIAMINOPROPANE AND AN EXOGENOUS BRIDGING LIGAND

Authors
NAKAO Y OOHATA Y FUJIWARA R ITADANI M SAKURAI T ICHIMURA A MORI W
Citation
Y. Nakao et al., PREPARATION AND PROPERTIES OF THE DINUCLEAR COPPER(II) COMPLEXES CONTAINING THE DERIVATIVES OF S(2-BENZIMIDAZOLYL)!-2-HYDROXY-1,3-DIAMINOPROPANE AND AN EXOGENOUS BRIDGING LIGAND, Bulletin of the Chemical Society of Japan, 66(7), 1993, pp. 2112-2114
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
66
Issue
7
Year of publication
1993
Pages
2112 - 2114
Database
ISI
SICI code
0009-2673(1993)66:7<2112:PAPOTD>2.0.ZU;2-W
Abstract
The dinuclear copper(II) complexes of HL-Et or HL-Me and a bridging li gand (X(X=N3-, NCS-, NCO-, OH-, OAc-, (CH3)3CCOO- (OPi-), o-C6H4 (CH3) COO-(OTo-), pyrazolate (Pz-), and imidazolate (Im-))) have been prepar ed and characterized, where enzimidazolyl)methyl!-2-hydroxy-1,3-diamin opropane and nzimidazolyl)methyl!-2-hydroxy-1,3-diaminopropane. The ma gnetic moments of these complexes differ depending upon their bridging groups. The electrochemistry in N,N-dimethylformamide showed that onl y one-electron reduction-(Cu2+-Cu2+-->Cu+-Cu2+) can occur for the dinu clear complexes bridged by X=N3-, OAc-, OPi-, OTo-, Pz-, whilst the ot her complexes showed irreversible processes.