LITHIUM WATER INTERACTIONS - EXPERIMENTS AND ANALYSIS

The interaction of molten-lithium droplets with water is studied exper imentally. In one set of experiments, droplets of approximately 10- to 15-mm diameter are injected into a vessel filled with water. The reac tion is filmed, and pressure measurements are made. The initial metal and water temperatures range from 200 to 500-degrees-C and 20 to 70-de grees-C, respectively. It is found that when reactant temperatures are high, an explosive reaction often occurs. When the initial lithium te mperature is >400-degrees-C and the water is >30-degrees-C, the explos ive reactions become much more probable, with pressure peaks as high a s 4 MPa. The reaction is modeled to explain the temperature threshold for this metal-ignition phenomena. Results with the model support the hypothesis that explosive reactions occur when the lithium droplet sur face reaches its saturation temperature while the hydrogen film surrou nding the drop is relatively thin. A second set of experiments measure s the reaction rate of nonexplosive lithium- water reactions. The test geometry parallels that of the previous experiments, and the reactant temperature combinations are deliberately kept below the observed ign ition threshold. Two separate methods are used to determine the reacti on rate in each test: One uses a three-color pyrometer to measure the drop temperature as the lithium rises through the water, while the oth er consists of a photographic technique that measures the amount of hy drogen generated. Measured reaction rates range from approximately 10 to 50 mol/s.m2 with good agreement between the two measurement techniq ues. The data do not show any significant variation in the reaction ra te as a function of either the initial water or initial lithium temper ature.