COVALENT ATTACHMENT OF 2 IMPORTANT DICOPPER(II) SYSTEMS IN A ONE-DIMENSIONAL POLYMERIC CHAIN - AN X-RAY STRUCTURE OF (CU2(EN)2(OH)2.CU2(O2CME)4)(PF6)2.0.5ETOH!ALPHA SHOWING THE SHORTEST CU ... CU DISTANCE IN THE TETRAACETATO CORE

Authors
MEENAKUMARI S CHAKRAVARTY AR
Citation
S. Meenakumari et Ar. Chakravarty, COVALENT ATTACHMENT OF 2 IMPORTANT DICOPPER(II) SYSTEMS IN A ONE-DIMENSIONAL POLYMERIC CHAIN - AN X-RAY STRUCTURE OF (CU2(EN)2(OH)2.CU2(O2CME)4)(PF6)2.0.5ETOH!ALPHA SHOWING THE SHORTEST CU ... CU DISTANCE IN THE TETRAACETATO CORE, Polyhedron, 12(14), 1993, pp. 1825-1827
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
12
Issue
14
Year of publication
1993
Pages
1825 - 1827
Database
ISI
SICI code
0277-5387(1993)12:14<1825:CAO2ID>2.0.ZU;2-O
Abstract
Reaction of Cu2(O2CMe)4(H2O)2 with 1,2-diaminoethane(en) in ethanol, f ollowed by the addition of NH4PF6, led to the formation of a covalentl y linked 1D polymeric copper(II) title complex showing alternating {Cu 2(en)2(OH)22+} and {Cu2(O2CMe)4} units in the chain and the shortest C u...Cu separation of 2.558(2) angstrom in the tetraacetato core.