Ai. Marshakov et Np. Chebotareva, EFFECT OF OXYGEN-CONTAINING OXIDANTS ON TIN CORROSION AND ITS ELECTROCHEMICAL-BEHAVIOR IN ACIDIC SOLUTIONS, Protection of metals, 28(6), 1992, pp. 714-719
The effect of oxygen-containing oxidants on the corrosion and the elec
trochemical behavior of tin in acidic solutions was studied. It was fo
und, that like iron and zinc, tin dissolution at constant potential is
activated by the presence of oxygen-containing oxidants. At high cath
odic polarization and in the presence of nitrate, nitrite and sulfate
ions the tin dissolution rate is higher than at the zero-current poten
tial. It is assumed, that the oxidizing agents promote the cathodic re
action of the tin-hydride formation, where their reduction products se
rve as proton donors in the process.