SYNTHESIS OF N-ARYLHYDROXYLAMINES BY ANTIMONY-CATALYZED REDUCTION OF NITROARENES

Authors
REN PD DONG TW WU SH
Citation
Pd. Ren et al., SYNTHESIS OF N-ARYLHYDROXYLAMINES BY ANTIMONY-CATALYZED REDUCTION OF NITROARENES, Synthetic communications, 27(9), 1997, pp. 1547-1552
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
27
Issue
9
Year of publication
1997
Pages
1547 - 1552
Database
ISI
SICI code
0039-7911(1997)27:9<1547:SONBAR>2.0.ZU;2-7
Abstract
Metallic antimony catalyzes the reduction of aromatic nitro compounds to the corresponding N-arylhydroxylamines in good yields with NaBH4 un der mild conditions. The azoxybenzenes from autoxidation of N-arylhydr oxylamines were also obtained in basic conditions.