Extracts of drinking water and effluents from municipal and industrial
sewage treatment plants were analysed by gas chromatography-mass spec
trometry and by high-performance liquid chromatography combined with u
ltraviolet and/or mass spectrometric detection. After column chromatog
raphy or flow-injection analysis bypassing the analytical column, ioni
zation was performed by a thermospray interface. Identification of the
pollutants was carried out by tandem mass spectrometry, generating da
ughter-ion spectra by collision-induced dissociation. Most pollutants
in drinking water and in the effluents of waste water treatment plants
are surface-active compounds of anthropogenic origin or their biochem
ical degradation products. Difficulties encountered during separation,
detection and identification are presented and discussed and techniqu
es for solving these problems are proposed.