DILUENT EFFECT ON THE EXTRACTION PROPERTIES OF BIFUNCTIONAL NEUTRAL ORGANOPHOSPHORUS COMPOUNDS (BNOPC) .2. DILUENT EFFECT ON THE EXTRACTIONPROPERTIES OF SYSTEMS WITH BNOPC

Authors
SHADRIN AY BABAIN VA KISELEVA RN
Citation
Ay. Shadrin et al., DILUENT EFFECT ON THE EXTRACTION PROPERTIES OF BIFUNCTIONAL NEUTRAL ORGANOPHOSPHORUS COMPOUNDS (BNOPC) .2. DILUENT EFFECT ON THE EXTRACTIONPROPERTIES OF SYSTEMS WITH BNOPC, Radiochemistry, 35(1), 1993, pp. 30-33
Citations number
8
Categorie Soggetti
Chemistry Analytical","Chemistry Inorganic & Nuclear
Journal title
Radiochemistry → ACNP
ISSN journal
10663622
Volume
35
Issue
1
Year of publication
1993
Pages
30 - 33
Database
ISI
SICI code
1066-3622(1993)35:1<30:DEOTEP>2.0.ZU;2-D
Abstract
The diluent effect on the extraction properties of diphenyl(dibutylcar bamoylmethylene)phosphine oxide can be described by the equation 1gD = -9.69 + 22.1 epsilon-1/2epsilon+1 + 4.20 n0(2)-1/n0(2)+1. The correla tion coefficient between the calculated and experimental values was 0. 96. It is suggested that a water molecule dissolved in the organic pha se reacts with H atoms of the bridging methylene.