DILUENT EFFECT ON THE EXTRACTION PROPERTIES OF BIFUNCTIONAL NEUTRAL ORGANOPHOSPHORUS COMPOUNDS (BNOPC) .2. DILUENT EFFECT ON THE EXTRACTIONPROPERTIES OF SYSTEMS WITH BNOPC
Ay. Shadrin et al., DILUENT EFFECT ON THE EXTRACTION PROPERTIES OF BIFUNCTIONAL NEUTRAL ORGANOPHOSPHORUS COMPOUNDS (BNOPC) .2. DILUENT EFFECT ON THE EXTRACTIONPROPERTIES OF SYSTEMS WITH BNOPC, Radiochemistry, 35(1), 1993, pp. 30-33
The diluent effect on the extraction properties of diphenyl(dibutylcar
bamoylmethylene)phosphine oxide can be described by the equation 1gD =
-9.69 + 22.1 epsilon-1/2epsilon+1 + 4.20 n0(2)-1/n0(2)+1. The correla
tion coefficient between the calculated and experimental values was 0.
96. It is suggested that a water molecule dissolved in the organic pha
se reacts with H atoms of the bridging methylene.