DILUENT EFFECT ON THE EXTRACTION PROPERTIES OF BIFUNCTIONAL NEUTRAL ORGANOPHOSPHORUS COMPOUNDS .3. DILUENT EFFECT ON THE EXTRACTION PROPERTIES OF DIPHOSPHINE DIOXIDES WITH SUBSTITUTED METHYLENE BRIDGES

Authors
SHADRIN AY SMIRNOV IV KISELEVA RN NESTEROVA NP POLIKARPOV YM KABACHNIK MI
Citation
Ay. Shadrin et al., DILUENT EFFECT ON THE EXTRACTION PROPERTIES OF BIFUNCTIONAL NEUTRAL ORGANOPHOSPHORUS COMPOUNDS .3. DILUENT EFFECT ON THE EXTRACTION PROPERTIES OF DIPHOSPHINE DIOXIDES WITH SUBSTITUTED METHYLENE BRIDGES, Radiochemistry, 35(1), 1993, pp. 34-38
Citations number
7
Categorie Soggetti
Chemistry Analytical","Chemistry Inorganic & Nuclear
Journal title
Radiochemistry → ACNP
ISSN journal
10663622
Volume
35
Issue
1
Year of publication
1993
Pages
34 - 38
Database
ISI
SICI code
1066-3622(1993)35:1<34:DEOTEP>2.0.ZU;2-9
Abstract
The extraction properties of diphosphine dioxides containing substitut ed methylene bridges are studied for REE and TPE in various diluents. The diluent properties are demonstrated much less to affect the extrac tion properties of the diphosphine dioxides containing one or two subs tituents on the methylene bridge than those of dioxides without substi tuents. This is probably due to both a decrease of the methylene H aci dity after adding the substituent and steric hindrances.