A STUDY OF ROMAN GLASS BY REFLECTANCE AND ELECTRON-PARAMAGNETIC-RESONANCE SPECTROSCOPIES

Reflectance and electron paramagnetic resonance (EPR) spectroscopies w ere used to study 25 fragments of Roman glass. Colour coordinates were used for an unbiased classification of the glasses in colour groups, which accounted for the presence of blue, blue-green, green, yellow-gr een, yellow and purple samples. Reflectance spectra were recorded in t he 250-2500 nm wavelength range and showed absorption bands characteri stic of Fe(II), Fe(III) and Mn(III) ions; furthermore, Co(II) and Cu(I I) bands were observed in the spectra of the blue glasses. A decrease of the absorbance ratio of Fe(II) to Fe(III) ions was observed moving from blue-green to green and yellow-green glasses; however, yellow fra gments still proved to be reduced glasses. EPR spectra displayed the c haracteristic patterns of Fe(III) and Mn(II) ions, with g-values in th e 2-5 interval and spectral features depending on the relative content of the two elements. The characteristic pattern of the V(IV) ion (g a lmost-equal-to 2) and signals due to the formation of iron-sulphur com plexes (g almost-equal-to 6) appeared in the spectrum of a dark yellow glass, recorded at 77 K.