SUBSTITUENT CONTROL OVER THE REGIOCHEMISTRY OF RING-OPENING OF 2-AZIRIDINYLMETHYL RADICALS

Authors
SCHWAN AL REFVIK MD
Citation
Al. Schwan et Md. Refvik, SUBSTITUENT CONTROL OVER THE REGIOCHEMISTRY OF RING-OPENING OF 2-AZIRIDINYLMETHYL RADICALS, Tetrahedron letters, 34(31), 1993, pp. 4901-4904
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
31
Year of publication
1993
Pages
4901 - 4904
Database
ISI
SICI code
0040-4039(1993)34:31<4901:SCOTRO>2.0.ZU;2-1
Abstract
Several substituted 2-aziridinylmethyl radicals have been generated an d a rapid ring opening ensues to produce aminyl radicals by way of C-N bond cleavage and in some instances alpha-aminyl carbon radicals via C-C bond homolysis.