TRIISOPROPYLSILYLDIAZOMETHANE - A NEW STABLE REAGENT FOR ESTERIFICATION

Citation
Ja. Soderquist et Ei. Miranda, TRIISOPROPYLSILYLDIAZOMETHANE - A NEW STABLE REAGENT FOR ESTERIFICATION, Tetrahedron letters, 34(31), 1993, pp. 4905-4908
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
34
Issue
31
Year of publication
1993
Pages
4905 - 4908
Database
ISI
SICI code
0040-4039(1993)34:31<4905:T-ANSR>2.0.ZU;2-K
Abstract
Triisopropylsilyldiazomethane (3), easily prepared in 96% yield from f ormyltriisopropylsilane tosythydrazone (2), undergoes smooth reaction with representative carboxylic acids to produce excellent yields of th e corresponding silylmethyl esters (4).