CYCLOALKANO-2H-PYRROLE AS A STABLE INTERMEDIATE IN THE CONVERSION OF BETA-CYCLOALKENYL-ALPHA-AZIDOACRYLATES TO CYCLOALKANO-1H-PYRROLES

Citation
C. Vogel et al., CYCLOALKANO-2H-PYRROLE AS A STABLE INTERMEDIATE IN THE CONVERSION OF BETA-CYCLOALKENYL-ALPHA-AZIDOACRYLATES TO CYCLOALKANO-1H-PYRROLES, Angewandte Chemie, International Edition in English, 32(7), 1993, pp. 1051-1052
Citations number
14
Categorie Soggetti
Chemistry
ISSN journal
05700833
Volume
32
Issue
7
Year of publication
1993
Pages
1051 - 1052
Database
ISI
SICI code
0570-0833(1993)32:7<1051:CAASII>2.0.ZU;2-Z
Abstract
A quantitative 1,5-electrocyclization takes place on thermolysis of th e 2-vinyl-cycloalkenyl-alpha-azidoacrylate 1 to form the substituted c ycloalkano-2H-pyrroles 2. Products of a reaction of vinyl azide or -ni trene with the unsaturated side chains were not observed.