WATER-SOLUBLE PHOSPHANES .1. A NEW ROUTE TO WATER-SOLUBLE PHOSPHANES WITH PARA-SULFONATED PHENYL SUBSTITUENTS - CRYSTAL-STRUCTURE OF P(C6H4-P-SO3K)3.KCL.0.5H2O

Authors
HERD O LANGHANS KP STELZER O WEFERLING N SHELDRICK WS
Citation
O. Herd et al., WATER-SOLUBLE PHOSPHANES .1. A NEW ROUTE TO WATER-SOLUBLE PHOSPHANES WITH PARA-SULFONATED PHENYL SUBSTITUENTS - CRYSTAL-STRUCTURE OF P(C6H4-P-SO3K)3.KCL.0.5H2O, Angewandte Chemie, International Edition in English, 32(7), 1993, pp. 1058-1059
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
7
Year of publication
1993
Pages
1058 - 1059
Database
ISI
SICI code
0570-0833(1993)32:7<1058:WP.ANR>2.0.ZU;2-X
Abstract
In the superbasic medium dimethylsulfoxide/KOH, potassium p-fluorobenz ene-sulfonate (1) can be treated with PH3 Eq. (a)!, or primary or sec ondary phosphanes to afford water-soluble phosphanes (3) containing su lfonated aromatic groups. The trianion P(C6H4-p-SO3-)3! in 2 . KCl . 0.5H2O is the first in this class of compounds that could be character ized by X-ray crystallography.