STRUCTURAL EVIDENCE OF THE AROMATICITY OF BOREPINS - A COMPARISON OF 1-CHLOROBOREPIN AND TRICARBONYL(1-CHLOROBOREPIN)MOLYBDENUM

Authors
ASHE AJ KAMPF JW KLEIN W ROUSSEAU R
Citation
Aj. Ashe et al., STRUCTURAL EVIDENCE OF THE AROMATICITY OF BOREPINS - A COMPARISON OF 1-CHLOROBOREPIN AND TRICARBONYL(1-CHLOROBOREPIN)MOLYBDENUM, Angewandte Chemie, International Edition in English, 32(7), 1993, pp. 1065-1066
Citations number
37
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
7
Year of publication
1993
Pages
1065 - 1066
Database
ISI
SICI code
0570-0833(1993)32:7<1065:SEOTAO>2.0.ZU;2-A
Abstract
A planar structure with C2v symmetry is a description of 1-chloroborep in 1, and is consistent with the presumption that 1 and probably also 1H-borepin are aromatic compounds. The Mo(CO)3 complex was prepared fr om 1. Its structure was also determined, and it could be reduced to th e stable complex 2.