ORGANOMETALLIC MOLECULAR TREES AS MULTIELECTRON AND MULTIPROTON RESERVOIRS - CPFE-INDUCED NONAALLYLATION OF MESITYLENE AND PHASE-TRANSFER-CATALYZED SYNTHESIS OF A REDOX-ACTIVE NONAIRON COMPLEX()

Authors
MOULINES F DJAKOVITCH L BOESE R GLOAGUEN B THIEL W FILLAUT JL DELVILLE MH ASTRUC D
Citation
F. Moulines et al., ORGANOMETALLIC MOLECULAR TREES AS MULTIELECTRON AND MULTIPROTON RESERVOIRS - CPFE-INDUCED NONAALLYLATION OF MESITYLENE AND PHASE-TRANSFER-CATALYZED SYNTHESIS OF A REDOX-ACTIVE NONAIRON COMPLEX(), Angewandte Chemie, International Edition in English, 32(7), 1993, pp. 1075-1077
Citations number
51
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
7
Year of publication
1993
Pages
1075 - 1077
Database
ISI
SICI code
0570-0833(1993)32:7<1075:OMTAMA>2.0.ZU;2-W
Abstract
A reservoir of 9 electrons and 27 protons, complex 1 has 8 +/- 1 quasi -equivalent redox centers. It is prepared from CpFe(eta6-mesitylene)! + by nonaallylation of the three methyl substituents, demetalation, co nversion into the corresponding nonaol, and phase-transfer-catalyzed r eaction with CpFe-(FC6H4Me)!.