ANSA-METALLOCENES OF CALCIUM AND STRONTIUM - ONE-POT SYNTHESIS OF ORGANOMETALLIC COMPLEXES OF THE HEAVIER ALKALINE-EARTH METALS

Authors
RIECKHOFF M PIEPER U STALKE D EDELMANN FT
Citation
M. Rieckhoff et al., ANSA-METALLOCENES OF CALCIUM AND STRONTIUM - ONE-POT SYNTHESIS OF ORGANOMETALLIC COMPLEXES OF THE HEAVIER ALKALINE-EARTH METALS, Angewandte Chemie, International Edition in English, 32(7), 1993, pp. 1079-1081
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
7
Year of publication
1993
Pages
1079 - 1081
Database
ISI
SICI code
0570-0833(1993)32:7<1079:AOCAS->2.0.ZU;2-6
Abstract
The reductive dimerization of 6,6-dialkylfulvenes by elemental calcium or strontium smoothly afforded the first ansa-metallocene derivatives of these metals. The bright red 1,4-diazadiene adduct 1 was character ized structurally.