InSb/GaSb quantum well structures have been prepared by atmospheric pr
essure metalorganic vapor phase epitaxy. Strong sharp photoluminescenc
e emission peaks with a full width at half-maximum of 6-11 meV were ob
tained for the quantum well structures with well thicknesses of 0.35-0
.88 nm, suggesting nearly atomically planar interfaces. The observed p
hotoluminescence transition energies are in excellent agreement with t
he calculated values using a standard finite square well model taking
into account strain. A broadening of the predominant photoluminescence
emission peak was observed for quantum well structures with well thic
knesses above 1 nm, indicating nonplanar growth.