Scanning tunnelling microscopy (STM) has been used to obtain images of
the bacterial polysaccharide xanthan gum. The polysaccharide was depo
sited onto highly oriented pyrolytic graphite from a concentrated (100
mg ml-1) aqueous dispersion. The viscoelastic deposit was sheared in
order to induce molecular alignment and then imaged in air. STM studie
s revealed aggregates of stiff, aligned rod-shaped molecules.