Severe wear of the ultra-high molecular weight polyethylene (UHMWPE) c
omponents of total joint replacements limits their long-term success.
In previous studies, the infrared spectra obtained on retrieved UHMWPE
components were interpreted as evidence that the UHMWPE oxidizes in v
ivo. In direct contrast, infrared spectroscopy of the retrieved UHMWPE
acetabular components examined in this study demonstrated adsorbed es
terified fatty acids, readily extractable by hexane, and no substantia
l evidence of in vivo oxidation. This emphasizes that special care mus
t be taken when using infrared spectroscopy to assess retrieved compon
ents.