The rapid decay of the excited state of the F centers in KBr:OH- has b
een measured by mean of a pump and probe technique with picosecond tim
e resolution. The lifetime of the F centers (tau approximately 1 mus a
t 77 K) is shortened in the OH- doped samples, to tau approximately 31
0 ps. The quenching of the normal radiative lifetime seems to be relat
ed to librational excitation of the OH- molecular ion.