S. Glanz et J. Stichlmair, MINIMUM ENERGY DEMAND OF DISTILLATION-COLUMNS WITH MULTIPLE FEEDS, Chemical engineering & technology, 20(2), 1997, pp. 93-100
Distillation columns with multiple feeds are often used in processes f
or the separation of multicomponent mixtures. The minimum energy deman
d of such columns is determined via the minimum reflux and reboil, res
pectively. A novel method for directly calculating the minimum reflux
ratio is presented in this paper. Applicable to ideal, nonideal and az
eotropic mixtures the method is based merely on the knowledge of vapor
-liquid equilibrium of the feed mixtures. This knowledge allows the de
termination of the internal concentration profile near the feed entry
and, in turn, the calculation of both minimum reflux and optimal seque
nce of feeds. This sequence of feeds depends on feed compositions and
product compositions, as well. Surprisingly, sometimes a multiple feed
entry requires a higher energy demand than premixing the feed streams
.