SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF PERBENZOIC-ACID-O-17,O-18,NITROSOBENZENE-O-17,O-18 AND NITROSOBENZENE-N-15

Authors
BLEASDALE C ELLIS MK FARMER PB GOLDING BT HANDLEY KF JONES P MCFARLANE W
Citation
C. Bleasdale et al., SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF PERBENZOIC-ACID-O-17,O-18,NITROSOBENZENE-O-17,O-18 AND NITROSOBENZENE-N-15, Journal of labelled compounds & radiopharmaceuticals, 33(8), 1993, pp. 739-746
Citations number
26
Categorie Soggetti
Chemistry Analytical","Pharmacology & Pharmacy
Journal title
Journal of labelled compounds & radiopharmaceuticals → ACNP
ISSN journal
03624803
Volume
33
Issue
8
Year of publication
1993
Pages
739 - 746
Database
ISI
SICI code
0362-4803(1993)33:8<739:SASCOP>2.0.ZU;2-5
Abstract
3-Chloroperbenzoic acid-O-17,O-18 was prepared from 3-chlorobenzoyl ch loride and hydrogen peroxide-O-17, O-18 (obtained by subjecting water- O-17,O-18 to an electric discharge) and used to oxidise aniline to nit rosobenzene-O-17,O-18. Nitrobenzene-N-15 was reduced to aniline-N-15, which was oxidised by 3-chloroperberizoic acid to nitrosobenzene-N-15. N-15 and O-17 NMR data are given for the corresponding labelled nitro sobenzene.