PHOTOELECTRON SPECTROSCOPIC STUDIES OF AN ALPHA-NITRONYL NITROXIDE RADICAL - MECHANISM OF FERROMAGNETIC INTERMOLECULAR INTERACTION

Authors
AWAGA K YOKOYAMA T FUKUDA T MASUDA S HARADA Y MARUYAMA Y SATO N
Citation
K. Awaga et al., PHOTOELECTRON SPECTROSCOPIC STUDIES OF AN ALPHA-NITRONYL NITROXIDE RADICAL - MECHANISM OF FERROMAGNETIC INTERMOLECULAR INTERACTION, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 232, 1993, pp. 27-34
Citations number
18
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
232
Year of publication
1993
Pages
27 - 34
Database
ISI
SICI code
1058-725X(1993)232:<27:PSSOAA>2.0.ZU;2-C
Abstract
An ultraviolet photoelectron spectrum of phenyl alpha-nitronyl nitroxi de (PNN) has been studied in the gas phase, in order to understand the potentiality of the alpha-nitronyl nitroxide radical family yielding ferromagnetic intermolecular coupling. The observed spectrum has been well interpreted with the help of CNDO-CI calculation. Very strong spi n polarization effect has been suggested, which is advantageous for th e intermolecular ferromagnetic coupling.