CRYSTAL-STRUCTURE AND ELECTRONIC-STATE OF THE ORGANIC FERROMAGNET, NITROPHENYL ALPHA-NITRONYL NITROXIDE RADICAL

Authors
AWAGA K INABE T YOKOYAMA T MARUYAMA Y
Citation
K. Awaga et al., CRYSTAL-STRUCTURE AND ELECTRONIC-STATE OF THE ORGANIC FERROMAGNET, NITROPHENYL ALPHA-NITRONYL NITROXIDE RADICAL, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 232, 1993, pp. 79-88
Citations number
27
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
232
Year of publication
1993
Pages
79 - 88
Database
ISI
SICI code
1058-725X(1993)232:<79:CAEOTO>2.0.ZU;2-F
Abstract
Three kinds of alpha-nitronyl nitroxides, including the organic ferrom agnet, p-nitrophenyl alpha-nitronyl nitroxide, have been structurally characterized. MO calculation has indicated that both of the spin and electronic polarization effects are much enhanced in this radical fami ly, and that the spin density distribution depends little on the subst ituent at the alpha position. The magneto-structural correlation is di scussed, based on the difference in the crystal structure.