MAGNETOSTRUCTURAL CORRELATIONS IN DIMERIC COPPER(II) CARBOXYLATES

Authors
OHBA S KATO M TOKII T MUTO Y STEWARD OW
Citation
S. Ohba et al., MAGNETOSTRUCTURAL CORRELATIONS IN DIMERIC COPPER(II) CARBOXYLATES, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 232, 1993, pp. 695-704
Citations number
21
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
232
Year of publication
1993
Pages
695 - 704
Database
ISI
SICI code
1058-725X(1993)232:<695:MCIDCC>2.0.ZU;2-X
Abstract
For dimeric copper(II) carboxylates, the most important factor determi ning the strength of the spin superexchange interactions is the electr onic structure of the carboxylato bridge. It also has been revealed th at the trigonal bipyramidal deformation of the coordination geometry a round the copper atoms, and the bending of the carboxylato bridge decr ease the antiferromagnetic interactions.