PREPARATION AND STRUCTURE OF (4-PICOLINIU M)2LNCL4(H2O3!CL (LN = EU,HO)

Authors
MACKENSTEDT D URLAND W
Citation
D. Mackenstedt et W. Urland, PREPARATION AND STRUCTURE OF (4-PICOLINIU M)2LNCL4(H2O3!CL (LN = EU,HO), Zeitschrift fur anorganische und allgemeine Chemie, 619(8), 1993, pp. 1393-1396
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
619
Issue
8
Year of publication
1993
Pages
1393 - 1396
Database
ISI
SICI code
0044-2313(1993)619:8<1393:PASO(M>2.0.ZU;2-S
Abstract
The complex water containing chlorides (4-Picolinium)2LnCl4(H2O)3!Cl (Ln = Eu, Ho) were prepared for the first time. The crystal structures were determined on single crystals by X-ray methods. The isotypic com pounds crystallize with triclinic symmetry, space group P1BAR, Z = 2. Surprisingly the structures contain the complex anions LnCl4(H2O)3!- (Ln = Eu, Ho) where the ligands form a distorted pentagonal bipyramid, which to our knowledge has not been observed in lanthanide compounds till now.