W. Uhlig, SYNTHESIS OF FUNCTIONAL SUBSTITUTED DISIL ANES ON THE BASIS OF TRIFLATE DERIVATIVES, Zeitschrift fur anorganische und allgemeine Chemie, 619(8), 1993, pp. 1479-1482
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
Functional substituted disilanes are prepared by reaction of phenylate
d disilanes with trifluoromethane-sulfonic acid. Reduction of the trif
late derivatives with LiAlH4 leads to Si-H substituted disilanes. The
chlorinated disilanes are obtained by reaction of the triflate derivat
ives with Et3NHCl. Chloro-hydrogen substituted disilanes are prepared
by combination of both reaction types. The preparation of these compou
nds in a high purity is difficult on other ways.