Simulation of hypersonic reacting flows is a challenging task, due not
only to the large variety of applications (e.g. reentry problems of s
pace vehicles or supersonic combustion etc.) but also to the fact that
a large amount of computational and numerical efforts have to be made
in order to overcome the difficulties in,the numerical solution of th
e governing Navier Stokes equations. Whereas very often mathematical m
odelling is simplified by neglecting second-order effects like molecul
ar transport, thus solving the Euler equations, several interesting ph
enomena such as gas surface interactions require the solution of the f
ull set of Navier-Stokes equations. The algorithm presented here is ba
sed on a fully conservative formulation of the conservation equations
and uses a first-order flux-splitting scheme. The large system of ordi
nary differential and algebraic equations resulting from the spatial d
iscretization is solved by a time-accurate implicit extrapolation meth
od. In comparing two different nonequilibrium reaction schemes we show
that finite rate chemistry has a strong influence on the computed flo
wfield, e.g. the maximum temperature in the shock wave or the species
concentrations.