VITAMIN-B(12) DERIVATIVES AS ANION CARRIERS IN TRANSPORT THROUGH SUPPORTED LIQUID MEMBRANES AND CORRELATION WITH THEIR BEHAVIOR IN ION-SELECTIVE ELECTRODES

Authors
PALET C MUNOZ M DAUNERT S BACHAS LG VALIENTE M
Citation
C. Palet et al., VITAMIN-B(12) DERIVATIVES AS ANION CARRIERS IN TRANSPORT THROUGH SUPPORTED LIQUID MEMBRANES AND CORRELATION WITH THEIR BEHAVIOR IN ION-SELECTIVE ELECTRODES, Analytical chemistry, 65(11), 1993, pp. 1533-1536
Citations number
30
Categorie Soggetti
Chemistry Analytical
Journal title
Analytical chemistry → ACNP
ISSN journal
00032700
Volume
65
Issue
11
Year of publication
1993
Pages
1533 - 1536
Database
ISI
SICI code
0003-2700(1993)65:11<1533:VDAACI>2.0.ZU;2-V
Abstract
Two derivatives of vitamin B12, aquocyanocobalt-(III) heptapropylcobyr inate (HPC) and aquocyanocobalt-(III) heptamethylcobyrinate (HMC), wer e synthesized and used as anion carriers in supported liquid membranes . More efficient transport was observed when the more lipophilic carri er (i.e., HPC) was used. The effect of several parameters such as the carrier concentration and the composition of the stripping solution on the permeability of the membranes were investigated. The properties o f these transport systems were related to the response behavior of ISE s that are based on the HPC carrier.