We continue our study of orthogonal Lie algebras, i.e. Lie algebras wh
ich support an invariant scalar product. We first show that a Lie alge
bra has a non degenerate invariant bilinear form iff adjoint and coadj
oint representations are isomorphic. We study the space of all invaria
nt bilinear forms on an orthogonal algebra. In a second part we study
orthogonal modules and give a complete description of the double exten
sion process which allows to construct all orthogonal modules ; we giv
e examples and raise the question of existence of non-isomorphic ortho
gonal structures on a given orthogonal Lie algebra.