We have used molecular-beam epitaxy to grow high-quality pseudomorphic
Ni and Co1Ni9 films on Cu(001). From temperature-dependent surface ma
gneto-optic Kerr effect measurements of these films, we have determine
d the finite-size scaling behavior of the Curie temperature of ultrath
in films for a thickness range of n=2.5-16 monolayers (ML). The film t
hickness dependent Curie temperature for each of these ferromagnetic t
hin-film systems, T(C)(n), is described by a finite-size scaling formu
la: [T(C)(infinity) - Tc(n)]/T(C)(n) = [(n - n')/n0]-1/nu, where T(C)(
infinity) is the bulk Curie temperature, n0 = 2.5 +/- 0. 5 ML for Co f
ilms and 3.5 +/- 0.4 ML for Ni and Co1Ni9 films is the microscopic len
gth scale, and v=0.76 +/- 0.08 is the bulk correlation length exponent
. An interesting result is that Tc(n) extrapolates to zero in the sing
le mononolayer limit, n' = 1.