ON THE STEREOSELECTIVITY OF THE INTRAMOLECULAR DIOXENONE PHOTOCYCLOADDITION

Authors
Citation
Jd. Winkler et B. Shao, ON THE STEREOSELECTIVITY OF THE INTRAMOLECULAR DIOXENONE PHOTOCYCLOADDITION, Tetrahedron letters, 34(21), 1993, pp. 3355-3358
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
34
Issue
21
Year of publication
1993
Pages
3355 - 3358
Database
ISI
SICI code
0040-4039(1993)34:21<3355:OTSOTI>2.0.ZU;2-9
Abstract
The stereoselectivity of the intramolecular photocycloaddition of diox enone and enone substrates is compared. A mechanistic scheme that is c onsistent with the striking differences in the observed stereoselectiv ities is presented.