OPACIFIED SILICA AEROGEL POWDER INSULATION

Citation
E. Hummer et al., OPACIFIED SILICA AEROGEL POWDER INSULATION, Thermochimica acta, 218, 1993, pp. 269-276
Citations number
9
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00406031
Volume
218
Year of publication
1993
Pages
269 - 276
Database
ISI
SICI code
0040-6031(1993)218:<269:OSAPI>2.0.ZU;2-W
Abstract
We have investigated the thermal conductivity of powder and granular S iO2-aerogels with a density in the 80 to 150 kg/m3 range; the specimen s were opacified with carbon soot. The caloric measurements were perfo rmed as a function of temperature, gas pressure and mechanical load. T he smallest total conductivities for non-evacuated specimens are aroun d 0.017 W/(m.K) at 300 K. The extracted solid conductivities are in th e range 0.002 to 0.004 W/(m.K), depending on density, mechanical load and grain size; the radiative conductivity at 300 K is about 0.001 W/( m.K) for a fine powder; this corresponds to an extinction E almost-equ al-to 6000 m-1 or a specific extinction e = 60 m2/kg. For a coarse gra nular fill a considerably smaller specific extinction of e almost-equa l-to 20 m2/kg is found. The gaseous conductivity is about 0.013 to 0.0 17 W/(m.K), depending on the inter-grain pore space fraction. The inve stigated aerogel powders can be easily filled into hollow spacings and used as an effective non-evacuated insulation or, if evacuated, as a thermal superinsulation.