SYNTHESIS AND THE X-RAY CRYSTAL-STRUCTURE OF [(MU-H)OS5CU(CO)18(PPH3)]

Authors
ANG HG KWIK WL NG KH
Citation
Hg. Ang et al., SYNTHESIS AND THE X-RAY CRYSTAL-STRUCTURE OF [(MU-H)OS5CU(CO)18(PPH3)], Bulletin of the Chemical Society of Japan, 66(5), 1993, pp. 1438-1440
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
66
Issue
5
Year of publication
1993
Pages
1438 - 1440
Database
ISI
SICI code
0009-2673(1993)66:5<1438:SATXCO>2.0.ZU;2-D
Abstract
The hexanuclear bimetallic cluster [(mu-H)Os5Cu(CO)18(PPh3)] (1), was prepared from the reaction of [(mu-H)2Os3(CO)10] with CF3COOCuPPh3. 1 was shown by X-ray analysis to consist of a pentaosmium framework with a copper atom bridging four of the osmium atoms to form a puckered '' ladder-like'' arrangement based on four triangular units.