A CONVENIENT SYNTHESIS AND STRUCTURAL ASSESSMENT OF [SN(CH3)2(L(2)](CLO4)2

Authors
DEY D BAUL TSB RIVAROLA E
Citation
D. Dey et al., A CONVENIENT SYNTHESIS AND STRUCTURAL ASSESSMENT OF [SN(CH3)2(L(2)](CLO4)2, Bulletin of the Chemical Society of Japan, 66(5), 1993, pp. 1556-1558
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
66
Issue
5
Year of publication
1993
Pages
1556 - 1558
Database
ISI
SICI code
0009-2673(1993)66:5<1556:ACSASA>2.0.ZU;2-5
Abstract
A general synthesis for a novel class of complexes of the type, [Sn(CH 3)2(L2)](ClO4)2 (L=2-(substituted arylazo) pyridine) is reported. The structure of the complexes have been investigated by 119tin Mossbauer spectroscopy and NMR coupling constant ((SnCH))-Sn-117/119. Further, t he extent of distortion of tin-methyl groups in octahedral complexes h ave been calculated from the quadrupole shift (Q.S.) values using Pari sh's relationship.