Re. Summons et al., THE STRUCTURE OF A NEW C25 ISOPRENOID ALKENE BIOMARKER FROM DIATOMACEOUS MICROBIAL COMMUNITIES, Australian Journal of Chemistry, 46(6), 1993, pp. 907-915
A new C25 highly branched alkadiene (5) has been isolated from the dia
tomaceous benthic microbial communities of Hamelin Pool, Western Austr
alia. The structure (5) was determined by detailed n.m.r. and mass spe
ctral analysis, as well as by chemical degradation. Carbon isotopic me
asurements on this and related isoprenoids were consistent with an ori
gin from diatoms. The role of (5) and related metabolites as biologica
l marker compounds is discussed.