It is well known that product moment ratio estimators of the coefficie
nt of variation C(upsilon) skewness gamma, and kurtosis kappa exhibit
substantial bias and variance for the small (n less-than-or-equal-to 1
00) samples normally encountered in hydrologic applications. Consequen
tly, L moment ratio estimators, termed L coefficient of variation tau2
, L skewness tau3, and L kurtosis tau4 are now advocated because they
are nearly unbiased for all underlying distributions. The advantages o
f L moment ratio estimators over product moment ratio estimators are n
ot limited to small samples. Monte Carlo experiments reveal that produ
ct moment estimators of C(upsilon) and gamma are also remarkably biase
d for extremely large samples (n greater-than-or-equal-to 1000) from h
ighly skewed distributions. A case study using large samples (n greate
r-than-or-equal-to 5000) of average daily streamflow in Massachusetts
reveals that conventional moment diagrams based on estimates of produc
t moments C(upsilon), gamma, and kappa reveal almost no information ab
out the distributional properties of daily streamflow, whereas L momen
t diagrams based on estimators of tau2, tau3, and tau4 enabled us to d
iscriminate among alternate distributional hypotheses.