A NEW SYNTHETIC ROUTE FOR MONO-TIN(IV) AND POLY-TIN(IV) OXALATE ADDUCTS - IR AND MOSSBAUER STUDY

Authors
GUEYE O QAMAR H DIOP L DIOP CA RUSSO U
Citation
O. Gueye et al., A NEW SYNTHETIC ROUTE FOR MONO-TIN(IV) AND POLY-TIN(IV) OXALATE ADDUCTS - IR AND MOSSBAUER STUDY, Polyhedron, 12(10), 1993, pp. 1245-1249
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
12
Issue
10
Year of publication
1993
Pages
1245 - 1249
Database
ISI
SICI code
0277-5387(1993)12:10<1245:ANSRFM>2.0.ZU;2-7
Abstract
A new synthetic route to prepare mono- and poly-tin(IV) complexes with the oxalate anion is reported. It behaves either as a mono- or bichel ating terminal ligand, or as a bi- or tetra-unidentate bridging ligand , according to the experimental conditions. Possible structures for th ese complexes are proposed on the basis of IR and Mossbauer spectrosco pic data.