REACTIONS OF COORDINATED BETA-KETOESTERS - A NEW ROUTE FOR THE SYNTHESIS OF 4-SUBSTITUTED-3-METHYL PHENYL-1-PHENYL PYRAZOL-5-ONES VIA A METAL CHELATED STABLE INTERMEDIATE

Authors
SAMATH SA JEYASUBRAMANIAN K THAMBIDURAI S KAMARDEEN S RAMALINGAM SK
Citation
Sa. Samath et al., REACTIONS OF COORDINATED BETA-KETOESTERS - A NEW ROUTE FOR THE SYNTHESIS OF 4-SUBSTITUTED-3-METHYL PHENYL-1-PHENYL PYRAZOL-5-ONES VIA A METAL CHELATED STABLE INTERMEDIATE, Polyhedron, 12(10), 1993, pp. 1265-1267
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
12
Issue
10
Year of publication
1993
Pages
1265 - 1267
Database
ISI
SICI code
0277-5387(1993)12:10<1265:ROCB-A>2.0.ZU;2-N
Abstract
Unsubstituted and gamma-substituted copper(II) complexes of beta-ketoe sters on treatment with phenylhydrazine give ring-rearranged chelate i ntermediates, which on subsequent demetallation afford the new 4-halo/ phenylamido-3-methyl/phenyl-1-phenyl pyrazol-5-ones. ones.