The introduction of hydrophobic cyclodextrin derivatives as chiral sel
ectors in enantioselective gas chromatography has resulted in the wide
use of this analytical method in solving stereochemical problems. The
extraordinary separation efficiency of capillary gas chromatography e
nables the investigation of chiral constituents in complex mixtures su
ch as essential oils, pheromones or environmental samples. Enantiosele
ctive gas chromatography features high precision in the detection of m
inute enantiomeric impurities and detection limits are independent of
functional groups.